It was hard finding these! The first clip is a teaser put together by a South American fansub group. The two RealMedia clips that follow are the opening and closing animation + tune of Arrow Emblem
There are also two files in RealMedia format. These were the only versions I could find online in 2006.
Thanks to YouTube and Anime Music Videos.org I've found an AMV that was made for Arrow Emblem. It was created by Jusu85, back in 2006. It's set to Within Temptation's Our Farewell. Be aware that the AMV does contain spoilers.
YouTube user AnimeSRW was cool enough to make a compilation of videos of Takaya and Isabel. View the original over here.
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All content, with exception of "borrowed" blogpost images, or unless otherwise indicated, is copyright of Thomas Sluyter. The character Kilala the cat-demon is copyright of Rumiko Takahashi and used here without permission.